Li Zi-Jian, Ju Yu, Yu Bowen, Wu Xiaoling, Lu Huangjie, Li Yongxin, Zhou Jing, Guo Xiaofeng, Zhang Zhi-Hui, Lin Jian, Wang Jian-Qiang, Wang Shuao
Key Laboratory of Interfacial Physics and Technology, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, 2019 Jia Luo Road, Shanghai 201800, China.
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore.
Chem Commun (Camb). 2020 Jun 18;56(49):6715-6718. doi: 10.1039/d0cc02841j.
Modulated synthesis and isoreticular expansion of Th-MOFs enable the stepwise construction of hierarchical complexes in which porosity and functionality can be fine-tuned, affording new Th-MOFs with a record high void space (74.0%), the largest surface area (3396.5 m2 g-1) among thorium materials, and excellent adsorption capacities toward radioactive iodine.
钍基金属有机框架材料（Th-MOFs）的调制合成和等规扩展能够逐步构建分级复合物，其中孔隙率和功能性可以得到微调，从而提供具有创纪录高空隙率（74.0%）、钍材料中最大表面积（3396.5 m² g⁻¹）以及对放射性碘具有优异吸附能力的新型Th-MOFs。
