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格拉斯:元素周期表的发源地。

Glass: Home of the Periodic Table.

作者信息

Shakhgildyan Georgiy, Lipatiev Alexey, Lotarev Sergey, Fedotov Sergey, Sigaev Vladimir

机构信息

Department of Glass and Glass-Ceramics, Mendeleev University, Moscow, Russia.

出版信息

Front Chem. 2020 Apr 30;8:384. doi: 10.3389/fchem.2020.00384. eCollection 2020.

DOI:10.3389/fchem.2020.00384
PMID:32426331
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7203499/
Abstract

Glass is the most common material around us, and humankind uses it every day for more than 5000 years. However, from the chemical point of view, glass is the only material that could represent almost all elements of the Periodic Table inside itself, showing the effect of the Periodic Law on properties of the final material. In this paper, we show the most remarkable examples demonstrating that glass can rightfully be called "home" for all chemical elements providing different properties depending on its composition. We gave a new look at the Periodic Table and described how a small number of glass-forming components creates unique glass structure which could enclose almost all remaining elements including transition and noble metals, lanthanides and actinides as modifying components providing an inconceivable number of discoveries in material science. Moreover, we reviewed a series of studies on the direct femtosecond laser writing in glasses which paves the way for a redistribution of chemical elements in the spatially confined nanosized zone in glass volume providing unique properties of laser-induced structures. Finally, for the first time, we reproduce the Periodic Table in birefringence colors in the bulk of silica glass using a direct laser writing technique. This image of 3.6 × 2.4 mm size can withstand temperature up to 900°C, humidity, electromagnetic fields, powerful cosmic and reactor radiation and other environmental factors and demonstrates both the art of direct laser writing and symbolic role of glass as the safest and eternal home for the Periodic Table.

摘要

玻璃是我们周围最常见的材料,人类使用它已有5000多年的历史。然而,从化学角度来看,玻璃是唯一一种自身几乎可以包含元素周期表中所有元素的材料,这显示了元素周期律对最终材料性质的影响。在本文中,我们展示了最显著的例子,证明玻璃可以名正言顺地被称为所有化学元素的“家园”,其性质因其组成不同而各异。我们以全新视角审视了元素周期表,并描述了少量玻璃形成成分如何创造出独特的玻璃结构,这种结构能够容纳几乎所有其余元素,包括过渡金属和贵金属、镧系元素和锕系元素,这些元素作为改性成分,在材料科学领域带来了数不清的发现。此外,我们回顾了一系列关于在玻璃中进行直接飞秒激光写入的研究,这为玻璃体积内空间受限的纳米区域中化学元素的重新分布铺平了道路,赋予了激光诱导结构独特的性质。最后,我们首次使用直接激光写入技术在块状石英玻璃中再现了具有双折射颜色的元素周期表。这幅尺寸为3.6×2.4毫米的图像能够承受高达900°C的温度、湿度、电磁场、强烈的宇宙辐射和反应堆辐射以及其他环境因素,展示了直接激光写入技术的艺术性以及玻璃作为元素周期表最安全、永恒家园的象征意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2128/7203499/5e9a48bd74a7/fchem-08-00384-g0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2128/7203499/5e9a48bd74a7/fchem-08-00384-g0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2128/7203499/5e9a48bd74a7/fchem-08-00384-g0001.jpg

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本文引用的文献

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Control of Laser Induced Cumulative Stress for Efficient Processing of Fused Silica.用于高效加工熔融石英的激光诱导累积应力控制
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Direct femtosecond laser-induced formation of CdS quantum dots inside silicate glass.直接飞秒激光诱导在硅酸盐玻璃内形成 CdS 量子点。
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3-bit writing of information in nanoporous glass by a single sub-microsecond burst of femtosecond pulses.通过飞秒脉冲单次亚微秒脉冲串在纳米多孔玻璃中进行3位信息写入。
Opt Lett. 2018 Feb 15;43(4):851-854. doi: 10.1364/OL.43.000851.
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Multilevel data writing in nanoporous glass by a few femtosecond laser pulses.通过几个飞秒激光脉冲在纳米多孔玻璃中进行多级数据写入。
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Metallic glasses.金属玻璃。
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