Huaraca Luis F, Chamorro Soledad A, Hernández Víctor, Bay-Schmith Enrique, Villamar Cristina A
Centro de Investigación y Control Ambiental, Departamento de Ingeniería Civil y Ambiental, Escuela Politécnica Nacional, Quito, Ecuador.
Departamento de Ciencias Básicas, Facultad de Ciencias, Universidad Santo Tomás, Los Ángeles, Chile.
J Environ Sci Health B. 2020;55(7):646-654. doi: 10.1080/03601234.2020.1758497. Epub 2020 May 20.
The aim of this work was to know the differential composition of the dissolved fraction of a glyphosate-based herbicide (GBH), commercialized as GLIFOPAC, when reaches different aquatic environments and its ecotoxicological effects on crustaceans species living in them. , and were exposed to glyphosate herbicide called GLIFOPAC (480 g L of active ingredient or a.i.) at concentrations between 0.5 and 4.8 g a.i. L. Acute toxicity in (48 h-LC), (48 h-LC), and (96 h-LC) was studied. Chromatographic analysis of the GBH composition used and water (freshwater/sea water) polluted with GLIFOPAC were evaluated. Results reported acute toxicity (48-96 h-LC) values for and of 27.4 mg L, 806.4 mg L, and 19.4 mg L, respectively. Chromatographic evaluation described around 45 substances of the GLIFOPAC composition, such as from the surfactant structures (aliphatic chain with esther/ether group), metabolites (AMPA), and other substances (glucofuranose, glucopyranoside, galactopyranose). This study evidenced differences in the GLIFOPAC composition in freshwater and marine water, which may differentiate the toxic response at the crustacean-level in each aquatic environment.
这项工作的目的是了解一种以草甘膦为基础的除草剂(GBH)(商品名为GLIFOPAC)在进入不同水生环境时其溶解部分的差异组成,以及对生活在其中的甲壳类物种的生态毒理学影响。将大型溞、蚤状溞和中华哲水蚤暴露于名为GLIFOPAC的草甘膦除草剂(活性成分或有效成分含量为480 g/L),浓度范围为0.5至4.8 g有效成分/L。研究了大型溞(48小时半数致死浓度)、蚤状溞(48小时半数致死浓度)和中华哲水蚤(96小时半数致死浓度)的急性毒性。对所使用的GBH成分以及被GLIFOPAC污染的水(淡水/海水)进行了色谱分析评估。结果报告大型溞、蚤状溞和中华哲水蚤的急性毒性(48 - 96小时半数致死浓度)值分别为27.4 mg/L、806.4 mg/L和19.4 mg/L。色谱评估描述了GLIFOPAC成分中的约45种物质,如来自表面活性剂结构(带有酯/醚基团的脂肪链)、代谢物(氨甲基膦酸)和其他物质(呋喃葡萄糖、吡喃葡萄糖苷、吡喃半乳糖)。这项研究证明了GLIFOPAC在淡水和海水中的成分差异,这可能会使每个水生环境中甲壳类动物的毒性反应有所不同。