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磁性石墨烯/壳聚糖纳米复合材料:一种有前途的纳米吸附剂,用于从水溶液中去除 2-萘酚及其动力学研究。

Magnetic graphene/chitosan nanocomposite: A promising nano-adsorbent for the removal of 2-naphthol from aqueous solution and their kinetic studies.

机构信息

Department of Nanoscience and Technology, Bharathiar University, Coimbatore 641046, India.

Department of Chemical Engineering, Khalifa University of Science and Technology, P.O. Box 127788, Abu Dhabi, United Arab Emirates.

出版信息

Int J Biol Macromol. 2020 Sep 15;159:530-538. doi: 10.1016/j.ijbiomac.2020.05.113. Epub 2020 May 20.

Abstract

In this study, magnetic/graphene/chitosan nanocomposite (MGCH) is prepared through facile solvothermal process and employed as an adsorbent for the removal of 2-naphthol from aqueous solution. The physico-chemical characteristic results of FESEM, Raman, FTIR, XRD and VSM confirms that the MGCH nanocomposite is effectively prepared. The FESEM and EDS analysis reveals that the high density of spherical-like FeO nanoparticles and chitosan are successfully assembled on the surfaces of the graphene sheets. VSM result of MGCH composite exhibited higher saturation magnetization of 46.5 emu g and lower coercivity (H) of 50 O. This result discloses that MGCH possesses enough response required for the separation from aqueous solution. The batch mode adsorption studies demonstrates that MGCH based adsorbent showed almost 99.8% adsorption of 2-naphthol with a maximum adsorption capacity of 169.49 mg g at pH 2. Moreover, the kinetic studies of the samples are performed by fitting adsorption models to ensure the nature of the adsorption system. This work proves that MGCH nanocomposite can be used as high-performance adsorbent for removing of phenolic pollutants from contaminated wastewater.

摘要

在这项研究中,通过简便的溶剂热法制备了磁性/石墨烯/壳聚糖纳米复合材料(MGCH),并将其用作从水溶液中去除 2-萘酚的吸附剂。FESEM、拉曼、FTIR、XRD 和 VSM 的物理化学特性结果证实了 MGCH 纳米复合材料的有效制备。FESEM 和 EDS 分析表明,高密度的球形 FeO 纳米粒子和壳聚糖成功地组装在石墨烯片的表面上。MGCH 复合材料的 VSM 结果显示出较高的饱和磁化强度为 46.5 emu/g 和较低的矫顽力(H)为 50 O。该结果表明 MGCH 具有从水溶液中分离所需的足够响应。批式吸附研究表明,基于 MGCH 的吸附剂在 pH 2 时对 2-萘酚的吸附率几乎达到 99.8%,最大吸附容量为 169.49 mg/g。此外,通过拟合吸附模型对样品的动力学研究,以确保吸附系统的性质。这项工作证明了 MGCH 纳米复合材料可用作从受污染废水中去除酚类污染物的高性能吸附剂。

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