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基于环保的 b/r-CDs 比率荧光测试纸条对有机溶剂中痕量水的可视化监测。

Visual monitoring of trace water in organic solvents based on ecofriendly b/r-CDs ratiometric fluorescence test paper.

机构信息

School of Material Science and Engineering, Jiangsu University, 212013, Zhenjiang, PR China.

School of Chemistry and Chemical Engineering, Jiangsu University, 212013, Zhenjiang, PR China.

出版信息

Talanta. 2020 Aug 15;216:120958. doi: 10.1016/j.talanta.2020.120958. Epub 2020 Mar 25.

Abstract

Developing a green, non-toxic and easy to synthesize of fluorescence probe for fast and visual detecting trace water in various organic solvents was an important task. Here, a novel dual-emission fluorescence probe (b/r-CDs) was designed based on the red CDs (r-CDs) and blue CDs (b-CDs) to detect the trace water and enhance the visualization for naked-eye observation in different organic solvents. Among, the red fluorescence carbon dots (CDs) was found to have the capability to monitor trace amounts of water, which synthesized with green tea by facile ultrasonic method. Further, Such a dual-emission probe could fast monitor trace water in various organic solvents with high stability and fast response. Importantly, a synergistic mechanism of the dynamic process (b-CDs) and static quenching (r-CDs) was proved for the study of water detection. Moreover, the test paper was made for detecting trace water in different organic solvents, achieving convenient and effective detection.

摘要

开发一种绿色、无毒且易于合成的荧光探针,用于快速、可视化检测各种有机溶剂中的痕量水,是一项重要任务。在这里,我们设计了一种新型的双发射荧光探针(b/r-CDs),基于红色 CDs(r-CDs)和蓝色 CDs(b-CDs)来检测痕量水,并增强在不同有机溶剂中的肉眼观察的可视化效果。其中,发现红色荧光碳点(CDs)具有监测痕量水的能力,它是通过简便的超声法用绿茶合成的。此外,这种双发射探针可以在各种有机溶剂中快速监测痕量水,具有高稳定性和快速响应。重要的是,通过动态过程(b-CDs)和静态猝灭(r-CDs)的协同机制证明了该探针用于水检测的原理。此外,我们还制备了用于检测不同有机溶剂中痕量水的试纸,实现了方便、有效的检测。

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