挥发性有机化合物对可切换铁基配位聚合物的共价合成后修饰：一种用于选择性传感器开发的通用策略。
Covalent post-synthetic modification of switchable iron-based coordination polymers by volatile organic compounds: a versatile strategy for selective sensor development.
作者信息
Resines-Urien Esther, Piñeiro-López Lucía, Fernandez-Bartolome Estefania, Gamonal Arturo, Garcia-Hernandez Mar, Sánchez Costa José
机构信息
IMDEA Nanociencia, C/Faraday 9, Ciudad Universitaria de Cantoblanco, 28049, Madrid, Spain.
Instituto de Ciencia de Materiales de Madrid, CSIC, C/Sor Juana Inés de la Cruz, 3, Campus de Cantoblanco, 28049, Madrid, Spain.
出版信息
Dalton Trans. 2020 Jun 9;49(22):7315-7318. doi: 10.1039/d0dt01533d.
A covalent post-synthetic modification is applied in one of the most relevant polymers to obtain unprecedented switchable spin crossover (SCO) materials. We also demonstrate that this material can be used as a selective chemo-sensor for VOCs (particularly, formaldehyde) thanks to solid/vapor reactions occurring between the polymer and the corresponding vapor.
一种共价后合成修饰应用于最相关的聚合物之一，以获得前所未有的可切换自旋交叉（SCO）材料。我们还证明，由于聚合物与相应蒸汽之间发生的固/气反应，这种材料可用作挥发性有机化合物（特别是甲醛）的选择性化学传感器。
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