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用层状双氢氧化物包覆不锈钢网(LDH-SSMs)实现油/水混合物的超快分离。

Ultrafast separation of oil/water mixtures with layered double hydroxide coated stainless steel meshes (LDH-SSMs).

作者信息

Xie Yan, Gu Yi-Hang, Meng Jiao, Yan Xi, Chen Yan, Guo Xiao-Jing, Lang Wan-Zhong

机构信息

The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, College of Chemistry and Materials Science, Shanghai Normal University, 100 Guilin Road, Shanghai 200234, China.

The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, College of Chemistry and Materials Science, Shanghai Normal University, 100 Guilin Road, Shanghai 200234, China.

出版信息

J Hazard Mater. 2020 Nov 5;398:122862. doi: 10.1016/j.jhazmat.2020.122862. Epub 2020 May 13.

DOI:10.1016/j.jhazmat.2020.122862
PMID:32473327
Abstract

With the frequent discharge of wastewater and leakage of oil accidents, it has gained much attention to treat oil and organic pollutants from water. Herein, a facile and environmentally friendly approach is presented to fabricate MgAlZn layered double hydroxide-coated stainless steel mesh (LDH-SSM) via hydrothermal method, which could be used to separate various oil/water mixtures due to its superhydrophilic and underwater superoleophobic property. The as-prepared mesh possesses selective separation performance for oil/water mixtures with separation efficiency higher than 99.2% and high water flux of ∼ 44.5 L m s under gravity-driven force. Such membrane shows an effective separation for oil/water mixtures and recyclability, as well as exhibit excellent superhydrophilicity, making it a prominent candidate for oily water remediation.

摘要

随着废水的频繁排放和石油泄漏事故的发生,从水中去除油类和有机污染物受到了广泛关注。在此,我们提出了一种简便且环保的方法,通过水热法制备镁铝锌层状双氢氧化物包覆不锈钢网(LDH-SSM),由于其超亲水性和水下超疏油性,可用于分离各种油/水混合物。所制备的网对油/水混合物具有选择性分离性能,分离效率高于99.2%,在重力驱动下具有约44.5 L m⁻² s⁻¹的高水通量。这种膜对油/水混合物具有有效的分离和可回收性,同时表现出优异的超亲水性,使其成为含油废水修复的突出候选材料。

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