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采用氧化锌-聚偏氟乙烯传感织物的嵌入式腐蚀传感

Embedded Corrosion Sensing with ZnO-PVDF Sensor Textiles.

作者信息

Chowdhury Tonoy, D'Souza Nandika, Ho Yee Hsien, Dahotre Narendra, Mahbub Ifana

机构信息

Department of Mechanical and Energy Engineering, University of North Texas, Denton, TX 76207, USA.

Department of Materials Science and Engineering; University of North Texas, Denton, TX 76207, USA.

出版信息

Sensors (Basel). 2020 May 28;20(11):3053. doi: 10.3390/s20113053.

Abstract

Corrosion in underground and submerged steel pipes is a global problem. Coatings serve as an impermeable barrier or a sacrificial element to the transport of corrosive fluids. When this barrier fails, corrosion in the metal initiates. There is a critical need for sensors at the metal/coating interface as an early alert system. Current options utilize metal sensors, leading to accelerating corrosion. In this paper, a non-conductive sensor textile as a viable solution was investigated. For this purpose, non-woven Zinc (II) Oxide-Polyvinylidene Fluoride (ZnO-PVDF) nanocomposite fiber textiles were prepared in a range of weight fractions (1%, 3%, and 5% ZnO) and placed at the coating/steel interface. The properties of ZnO-PVDF nanocomposite meshes were characterized using scanning electron microscopy (SEM), x-ray diffraction (XRD), Fourier transform infrared (FTIR) and meter. Electrochemical impedance spectroscopy (EIS) testing was performed during the immersion of the coated samples to validate the effectiveness of the sensor textile. The results offer a new option for sub-surface corrosion sensing using low cost, easily fabricated sensor textiles.

摘要

地下和水下钢管的腐蚀是一个全球性问题。涂层可作为一种防渗屏障或牺牲性元件来阻止腐蚀性流体的传输。当这种屏障失效时,金属中的腐蚀就会开始。作为早期预警系统,在金属/涂层界面处对传感器有着迫切需求。目前的选择是使用金属传感器,这会导致腐蚀加速。在本文中,研究了一种非导电传感器织物作为可行的解决方案。为此,制备了一系列重量分数(1%、3%和5%的氧化锌)的非织造氧化锌-聚偏二氟乙烯(ZnO-PVDF)纳米复合纤维织物,并将其置于涂层/钢界面处。使用扫描电子显微镜(SEM)、X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)和仪表对ZnO-PVDF纳米复合网的性能进行了表征。在涂层样品浸泡期间进行了电化学阻抗谱(EIS)测试,以验证传感器织物的有效性。研究结果为利用低成本、易于制造的传感器织物进行地下腐蚀传感提供了一种新选择。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/47b3/7308928/05a387339d07/sensors-20-03053-g001.jpg

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