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机械响应性自组装苝二酰亚胺薄膜

Mechanoresponsive Self-Assembled Perylene Bisimide Films.

作者信息

Adams Victoria, Cameron Joseph, Wallace Matthew, Draper Emily R

机构信息

School of Chemistry, University of Glasgow, Glasgow, G12 8QQ, UK.

School of Pharmacy, University of East Anglia, Norwich, NR4 7TJ, UK.

出版信息

Chemistry. 2020 Aug 6;26(44):9879-9882. doi: 10.1002/chem.202001805. Epub 2020 Jul 8.

DOI:10.1002/chem.202001805
PMID:32484600
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7522684/
Abstract

In this work, self-assembled amino-acid appended perylene bisimides (PBIs) have been studied that when processed into thin films change their resistivity in response to being bent. The PBIs assemble into structures in water and form thin films upon drying. These normally delicate thin films can be tolerant to bending, depending on the aggregates they form. Furthermore, the films then reversibly change their resistivity in response to this mechanical stimulus. This change is proportional to the degree of bending of the film giving them the potential to be used quantitatively to measure mechanical movement, such as in wearable devices.

摘要

在这项工作中,对自组装的 appended 氨基酸苝二酰亚胺(PBIs)进行了研究,当将其加工成薄膜时,它们会因弯曲而改变电阻率。PBIs 在水中组装成结构,并在干燥时形成薄膜。这些通常很脆弱的薄膜能够耐受弯曲,这取决于它们形成的聚集体。此外,这些薄膜随后会因这种机械刺激而可逆地改变其电阻率。这种变化与薄膜的弯曲程度成正比,这使它们有潜力被定量用于测量机械运动,例如在可穿戴设备中。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f702/7522684/806d3cf974ab/CHEM-26-9879-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f702/7522684/7d1d133728c2/CHEM-26-9879-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f702/7522684/d7f0905ce0aa/CHEM-26-9879-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f702/7522684/f3cfe499d555/CHEM-26-9879-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f702/7522684/806d3cf974ab/CHEM-26-9879-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f702/7522684/7d1d133728c2/CHEM-26-9879-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f702/7522684/d7f0905ce0aa/CHEM-26-9879-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f702/7522684/f3cfe499d555/CHEM-26-9879-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f702/7522684/806d3cf974ab/CHEM-26-9879-g005.jpg

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