用于合成含氮多环芳烃的二苯并蒽醌结构单元
Dibenzoanthradiquinone Building Blocks for the Synthesis of Nitrogenated Polycyclic Aromatic Hydrocarbons.
作者信息
Martínez Jose I, Mora-Fuentes Juan P, Carini Marco, Saeki Akinori, Melle-Franco Manuel, Mateo-Alonso Aurelio
机构信息
POLYMAT, University of the Basque Country UPV/EHU, Avenida de Tolosa 72, 20018 Donostia-San Sebastian, Spain.
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
出版信息
Org Lett. 2020 Jun 19;22(12):4737-4741. doi: 10.1021/acs.orglett.0c01536. Epub 2020 Jun 2.
A straightforward method for the synthesis of two dibenzo[,]anthracene-5,6,12,13-diquinone building blocks is reported. To showcase their usefulness, a series of dibenzo[,]anthracene nitrogenated derivatives have been synthesized that show different optoelectronic, redox, and charge transport properties, illustrating their potential as organic semiconductors.
报道了一种合成两种二苯并[，]蒽-5,6,12,13-二醌结构单元的直接方法。为了展示它们的实用性，已合成了一系列二苯并[，]蒽含氮衍生物，这些衍生物表现出不同的光电、氧化还原和电荷传输性质，说明了它们作为有机半导体的潜力。
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