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滑石粉填充聚乙烯复合材料的熔体流变学和挤出胀大特性

Melt rheology and extrudate swell properties of talc filled polyethylene compounds.

作者信息

Kalantar Mehrjerdi Adib, Bashir Tariq, Skrifvars Mikael

机构信息

Swedish Centre for Resource Recovery, University of Borås, 501 90 Borås, Sweden.

出版信息

Heliyon. 2020 May 27;6(5):e04060. doi: 10.1016/j.heliyon.2020.e04060. eCollection 2020 May.

Abstract

An experimental study of high-density polyethylene (HDPE) composites filled with talc (0-15 wt.%) was carried out to investigate the rheological properties. The apparent melt viscosity, melt density, and die-swell ratio () of the composites were measured at constant shear stress and constant shear rate by using a melt flow indexer and capillary rheometer. The experimental conditions were set to a temperature range from 190 to 220 °C for both apparatuses whereas a load range from 5 to 12.16 kg was selected for melt flow indexer and shear rate range from 1 to 10000 s for capillary rheometer. The initial study showed that the talc particulates did not influence the melt viscosity compared with the neat HDPE but decreased the elasticity of the polymer system. The HDPE/talc systems obeyed power-law model in shear stress-shear rate variations and were shear thinning, meanwhile, the die-swell increased with an increased wall shear rate and shear stress. The melt density of the composites increased linearly with an increase of the filler weight fraction and decreased with the increase of the testing temperature. The talc-HDPE composites showed compressible in the molten state.

摘要

开展了一项对填充有滑石粉(0 - 15重量%)的高密度聚乙烯(HDPE)复合材料的流变性能进行研究的实验。通过使用熔体流动指数仪和毛细管流变仪,在恒定剪切应力和恒定剪切速率下测量了复合材料的表观熔体粘度、熔体密度和挤出胀大比()。两种仪器的实验条件均设定为温度范围为190至220°C,而熔体流动指数仪的负载范围为5至12.16千克,毛细管流变仪的剪切速率范围为1至10000 s⁻¹。初步研究表明,与纯HDPE相比,滑石粉颗粒不影响熔体粘度,但降低了聚合物体系的弹性。HDPE/滑石粉体系在剪切应力 - 剪切速率变化中遵循幂律模型,呈剪切变稀,同时,挤出胀大随壁面剪切速率和剪切应力的增加而增大。复合材料的熔体密度随填料重量分数的增加呈线性增加,随测试温度的升高而降低。滑石粉 - HDPE复合材料在熔融状态下表现出可压缩性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bcb4/7260442/5c39a8a6aabe/gr1.jpg

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