Stanciu Nicoleta-Violeta, Stan Felicia, Fetecau Catalin
Center of Excellence Polymer Processing, Dunarea de Jos University of Galati, 47 Domneasca, 800 008 Galati, Romania.
Polymers (Basel). 2020 May 28;12(6):1230. doi: 10.3390/polym12061230.
Understanding the flow behavior of polymer/carbon nanotube composites prior to melt processing is important for optimizing the processing conditions and final product properties. In this study, the melt shear viscosity, specific volume and thermal conductivity of low-density polyethylene (LDPE) filled with multi-walled carbon nanotubes (MWCNTs) were investigated for representative processing conditions using capillary rheometry. The experimental results show a significant increase in the melt shear viscosity of the LDPE/MWCNT composite with nanotube loadings higher than 1 wt.%. Upon increasing shear rates, the composites flow like a power-law fluid, with a shear-thinning index less than 0.4. The specific volume decreases with increasing pressure and nanotube loading, while the transition temperature increases linearly with increasing pressure. The thermal conductivity of the LDPE/MWCNT composite is nearly independent of nanotube loading up to the thermal percolation threshold of 1 wt.% and increases linearly with further increases in nanotube loading, reaching 0.35 W/m·K at 5 wt.%. The Carreau-Winter and Cross viscosity models and Tait equation, respectively, are able to predict the shear viscosity and specific volume with a high level of accuracy. These results can be used not only to optimize processing conditions through simulation but also to establish structure-property relationships for the LDPE/MWCNT composites.
了解聚合物/碳纳米管复合材料在熔融加工之前的流动行为对于优化加工条件和最终产品性能至关重要。在本研究中,使用毛细管流变仪对填充多壁碳纳米管(MWCNT)的低密度聚乙烯(LDPE)在代表性加工条件下的熔体剪切粘度、比容和热导率进行了研究。实验结果表明,当纳米管负载量高于1 wt.%时,LDPE/MWCNT复合材料的熔体剪切粘度显著增加。随着剪切速率的增加,复合材料表现出幂律流体的流动特性,剪切变稀指数小于0.4。比容随压力和纳米管负载量的增加而减小,而转变温度随压力的增加呈线性升高。LDPE/MWCNT复合材料的热导率在纳米管负载量达到1 wt.%的热渗流阈值之前几乎与纳米管负载量无关,随着纳米管负载量的进一步增加呈线性增加,在5 wt.%时达到0.35 W/m·K。Carreau-Winter粘度模型和Cross粘度模型以及Tait方程分别能够高精度地预测剪切粘度和比容。这些结果不仅可用于通过模拟优化加工条件,还可用于建立LDPE/MWCNT复合材料的结构-性能关系。
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