解聚剂在锂催化羰基化合物硅氢化反应中的加速作用
Accelerating role of deaggregation agents in lithium-catalysed hydrosilylation of carbonyl compounds.
作者信息
Ruiz Cristina, Raya-Barón Álvaro, Ortuño Manuel A, Fernández Ignacio
机构信息
Department of Chemistry and Physics, Research centre CIAIMBITAL, Ctra. Sacramento, s/n, 04120 Almería, Spain.
出版信息
Dalton Trans. 2020 Jun 21;49(23):7932-7937. doi: 10.1039/d0dt01540g. Epub 2020 Jun 3.
PMID:32490461
Abstract
A combined computational and experimental approach demonstrates the accelerating role of deaggregation agents, especially HMPA, in the Li-catalysed hydrosilylation of acetophenone in THF solution under very mild conditions.
摘要
一种计算与实验相结合的方法表明，在非常温和的条件下，解聚剂，尤其是六甲基磷酰胺（HMPA），在四氢呋喃（THF）溶液中锂催化的苯乙酮硅氢化反应中起到了加速作用。
Zotero 插件