Environmental benign synthesis of Nano-SSZ-13 via FAU trans-crystallization: Enhanced NH-SCR performance on Cu-SSZ-13 with nano-size effect.

Small pore zeolites with chabazite structure have been commercialized for selective catalytic reduction (SCR) of nitrogen oxides (NO) with ammonium (NH) from diesel exhaust. However, conventional zeolite synthesis processes detrimental effects on the environment due to the consumption of large amount of water, organic templates. Thus, this study proposed a green synthesis process with addition of minimal amount of water, structure directing agent and shortened steps to prepare nano-sized SSZ-13 (0.12 μm) using trans-crystallization strategy and exhibited enhanced performance for NO removal after copper ion-exchange. The operation temperature window (NO conversion >90 %) as well as the SO and HO resistance over the green-route prepared nano-sized SSZ-13 (178-480 °C) outperformed the conventional SSZ-13 (29.8 μm, 211-438 °C) mainly due to the much shorter diffusion path. This clearly implied that the mass transportation was key for NH-SCR of NO on such small pore zeolite catalysts, which was further confirmed via an in-depth mass transportation calculation process. These results demonstrate that the Cu-nano-sized SSZ-13 prepared by the environmental benign route has great potential to act as a new generation of deNO catalyst for diesel exhaust and provided a guideline for researchers to develop new methods to synthesize nano-catalysts for air pollution control.