基于四苯乙烯的 PdL 金属笼，具有聚集诱导发光和刺激响应行为。
A tetraphenylethene-based PdL metallacage with aggregation-induced emission and stimuli-responsive behavior.
机构信息
National Demonstration Center for Experimental Chemistry Education, Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, P. R. China.
出版信息
Dalton Trans. 2020 Jun 23;49(24):8051-8055. doi: 10.1039/d0dt00469c.
A tetraphenylethene-based Pd2L4 metallacage was self-assembled from four TPE-pyridine ligands with two Pd2+ ions. This metallacage with D4 symmetry exhibited a classical aggregation-induced emission property in different solvents and reversible stimuli-responsive behaviour with chloride ions and silver ions, successively.
一个基于四苯乙烯的 Pd2L4 金属笼由四个 TPE-吡啶配体与两个 Pd2+ 离子自组装而成。这个具有 D4 对称性的金属笼在不同的溶剂中表现出经典的聚集诱导发光性质，并能依次与氯离子和银离子发生可逆的刺激响应行为。
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