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一种通过亲电芳香取代对原始石墨烯进行边缘特异性修饰的通用方法。

A versatile route to edge-specific modifications to pristine graphene by electrophilic aromatic substitution.

作者信息

Shellard Philippa M, Srisubin Thunyaporn, Hartmann Mirja, Butcher Joseph, Fei Fan, Cox Henry, McNamara Thomas P, McArdle Trevor, Shepherd Ashley M, Jacobs Robert M J, Waigh Thomas A, Flitsch Sabine L, Blanford Christopher F

机构信息

Department of Chemistry, University of Manchester, Oxford Road, Manchester, M13 9PL UK.

Manchester Institute of Biotechnology, University of Manchester, 131 Princess Street, Manchester, M1 7DN UK.

出版信息

J Mater Sci. 2020;55(24):10284-10302. doi: 10.1007/s10853-020-04662-y. Epub 2020 May 9.

DOI:10.1007/s10853-020-04662-y
PMID:32536720
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7266800/
Abstract

Electrophilic aromatic substitution produces edge-specific modifications to CVD graphene and graphene nanoplatelets that are suitable for specific attachment of biomolecules.

摘要

亲电芳香取代反应可对化学气相沉积法制备的石墨烯和石墨烯纳米片进行边缘特异性修饰，这些修饰适用于生物分子的特异性附着。

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J Phys Chem Lett. 2019 Sep 5;10(17):4788-4793. doi: 10.1021/acs.jpclett.9b02225. Epub 2019 Aug 8.
2
Selective electrochemical functionalization of the graphene edge.石墨烯边缘的选择性电化学功能化。
Chem Sci. 2018 Nov 5;10(3):936-942. doi: 10.1039/c8sc04083d. eCollection 2019 Jan 21.
3
Edge-Functionalized Graphene Nanoplatelets as Metal-Free Electrocatalysts for Dye-Sensitized Solar Cells.
边缘功能化石墨烯纳米片作为无金属染料敏化太阳能电池的电催化剂。
Adv Mater. 2019 Mar;31(13):e1804440. doi: 10.1002/adma.201804440. Epub 2018 Dec 9.
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Quenched Stochastic Optical Reconstruction Microscopy (qSTORM) with Graphene Oxide.用氧化石墨烯淬灭的随机光学重建显微镜（qSTORM）。
Sci Rep. 2018 Nov 16;8(1):16928. doi: 10.1038/s41598-018-35297-4.
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Quantum and electrochemical interplays in hydrogenated graphene.氢化石墨烯中的量子与电化学相互作用
Nat Commun. 2018 Feb 23;9(1):793. doi: 10.1038/s41467-018-03026-0.
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An integrated multi-layer 3D-fabrication of PDA/RGD coated graphene loaded PCL nanoscaffold for peripheral nerve restoration.用于周围神经修复的聚多巴胺/聚乙二醇化精氨酸-甘氨酸-天冬氨酸肽包被的石墨烯负载聚己内酯纳米支架的集成多层3D制造
Nat Commun. 2018 Jan 22;9(1):323. doi: 10.1038/s41467-017-02598-7.
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