Rheological Behavior of Polymer/Carbon Nanotube Composites: An Overview.

This paper reviews the current achievements regarding the rheological behavior of polymer-based nanocomposites containing carbon nanotubes (CNTs). These systems have been the subject of a very large number of scientific investigations in the last decades, due to the outstanding characteristics of CNTs that have allowed the formulation of nanostructured polymer-based materials with superior properties. However, the exploitation of the theoretical nanocomposite properties is strictly dependent on the complete dispersion of CNTs within the host matrix and on the consequent development of a huge interfacial region. In this context, a deep knowledge of the rheological behavior of CNT-containing systems is of fundamental importance, since the evaluation of the material's viscoelastic properties allows the gaining of fundamental information as far as the microstructure of nanofilled polymers is concerned. More specifically, the understanding of the rheological response of polymer/CNT nanocomposites reveals important details about the characteristics of the interface and the extent of interaction between the two components, hence allowing the optimization of the final properties in the resulting nanocomposites. As the literature contains plenty of reviews concerning the rheological behavior of polymer/CNT nanocomposites, this review paper will summarize the most significant thermoplastic matrices in terms of availability and relevant industrial applications.