Yang Liu, Zhang Chuanqing, Lu Hongfeng, Zheng Yuanhan, Liu Yifan
State Key Laboratory for Geomechanics and Deep Underground Engineering, China University of Mining and Technology (Beijing), Beijing 100083 China.
Guangzhou Marine Geological Survey, China Geological Survey, Guangzhou 510760, China.
ACS Omega. 2020 Jun 9;5(24):14564-14574. doi: 10.1021/acsomega.0c01269. eCollection 2020 Jun 23.
The water generated after the dissociation of gas hydrates is spontaneously imbibed into the matrix pores. It hinders the gas-water flow and decreases the pore pressure, which is not conducive to the continuous depressurization of hydrate sediments. However, there are few research studies on the imbibition capacity and the influencing factors of hydrate sediments. In this paper, spontaneous imbibition experiments are carried out on the samples of hydrate sediments. The imbibition capacity and its influencing factors are analyzed. The results show that as the spontaneous imbibition time increases, the peak of the T spectra also shifts to the right, indicating the formation of new larger-sized pores. When the imbibition time exceeds the critical point, the hydrate sediments instantly disperse and reach the maximum imbibition capacity status. The influencing factors of the imbibition capacity include the moisture content, dry-wet cycle, clay minerals content, solution salinity, permeability, and porosity. With the increase of the clay mineral content, the imbibition capacity increases rapidly, and the I/S mixed layer can significantly improve the imbibition capacity. As the number of dry-wet cycles increases, the imbibition capacity gradually increases. In addition, the imbibition capacity is inversely related to the moisture content and the solution salinity. Porosity and permeability have little effect on the imbibition capacity. This study is of great significance for understanding dissociation water retention and optimizing hydrate exploitation systems.
气体水合物分解后产生的水会自发地吸入基质孔隙中。它阻碍了气水流动并降低了孔隙压力,这不利于水合物沉积物的持续降压。然而,关于水合物沉积物的吸液能力及其影响因素的研究很少。本文对水合物沉积物样品进行了自发吸液实验。分析了吸液能力及其影响因素。结果表明,随着自发吸液时间的增加,T谱峰也向右移动,表明形成了新的更大尺寸的孔隙。当吸液时间超过临界点时,水合物沉积物立即分散并达到最大吸液能力状态。吸液能力的影响因素包括含水量、干湿循环、粘土矿物含量、溶液盐度、渗透率和孔隙率。随着粘土矿物含量的增加,吸液能力迅速增加,伊利石/蒙脱石混层可显著提高吸液能力。随着干湿循环次数的增加,吸液能力逐渐增加。此外,吸液能力与含水量和溶液盐度呈负相关。孔隙率和渗透率对吸液能力影响不大。本研究对于理解分解水的保留和优化水合物开采系统具有重要意义。