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三（二茂铁基亚甲基）苏曼烯：合成、光物理性质及其在水中高效识别铯阳离子的应用

Tris(ferrocenylmethidene)sumanene: synthesis, photophysical properties and applications for efficient caesium cation recognition in water.

作者信息

Kasprzak Artur, Kowalczyk Agata, Jagielska Agata, Wagner Barbara, Nowicka Anna M, Sakurai Hidehiro

机构信息

Faculty of Chemistry, Warsaw University of Technology, Noakowskiego Str. 3, 00-664 Warsaw, Poland.

出版信息

Dalton Trans. 2020 Aug 7;49(29):9965-9971. doi: 10.1039/d0dt01506g. Epub 2020 Jun 29.

DOI:10.1039/d0dt01506g
PMID:32597432
Abstract

The synthesis of a sumanene derivative bearing three ferrocenyl substituents is presented. This conjugated compound is solution-processable, shows red-light emission with high fluorescence quantum yield and can be used for the construction of the first buckybowl-based sensor for the selective and effective recognition of caesium cations (Cs) in aqueous solution.

摘要

本文介绍了一种带有三个二茂铁基取代基的苏曼烯衍生物的合成。这种共轭化合物可通过溶液法加工，具有高荧光量子产率的红光发射，可用于构建首个基于巴基碗的传感器，用于在水溶液中选择性有效地识别铯阳离子（Cs）。

相似文献

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Tris(ferrocenylmethidene)sumanene: synthesis, photophysical properties and applications for efficient caesium cation recognition in water.三（二茂铁基亚甲基）苏曼烯：合成、光物理性质及其在水中高效识别铯阳离子的应用
Dalton Trans. 2020 Aug 7;49(29):9965-9971. doi: 10.1039/d0dt01506g. Epub 2020 Jun 29.
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Synthesis of π-extended and bowl-shaped sumanene-ferrocene conjugates and their application in highly selective and sensitive cesium cations electrochemical sensors.π-扩展和碗状苏曼烯-二茂铁共轭物的合成及其在高选择性和灵敏性铯阳离子电化学传感器中的应用。
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A sumanene-containing magnetic nanoadsorbent for the removal of caesium salts from aqueous solutions.一种用于从水溶液中去除铯盐的含隅极面型石墨烯的磁性纳米吸附剂。
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Jet spectroscopy of buckybowl: electronic and vibrational structures in the S0 and S1 states of triphenylene and sumanene.巴基碗的喷射光谱：三苯烯和 sumanene 的 S0 和 S1 态的电子和振动结构。
J Chem Phys. 2013 Jul 28;139(4):044313. doi: 10.1063/1.4816636.

引用本文的文献

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Complexation by γ-cyclodextrin as a way of improving anticancer potential of sumanene.γ-环糊精的络合作用提高榄香烯的抗癌潜力。
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Application of Monoferrocenylsumanenes Derived from Sonogashira Cross-Coupling or Reactions in Highly Sensitive and Selective Cesium Cation Electrochemical Sensors.
Sonogashira 交叉偶联或反应衍生的单二茂铁基 sumanenes 在高灵敏和选择性铯离子电化学传感器中的应用。
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Fast, solvent-free synthesis of ferrocene-containing organic cages dynamic covalent chemistry in the solid state.固态中含二茂铁有机笼的快速无溶剂合成：动态共价化学
Chem Sci. 2022 Feb 3;13(10):2877-2883. doi: 10.1039/d1sc06372c. eCollection 2022 Mar 9.
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