Feng Shih-Wei, Wang Ying-Hsiang, Tsai Chin-Yi, Cheng Tzu-Huan, Wang Hsiang-Chen
Department of Applied Physics, National University of Kaohsiung No. 700, Kaohsiung University Road, Nan-Tzu Dist., 811, Kaohsiung City, Taiwan (R.O.C.).
LiveStrong Optoelectronics Cooperation, No. 82, Luke 5th Rd., Kaohsiung City, 821, Taiwan (R.O.C.).
Sci Rep. 2020 Jun 29;10(1):10539. doi: 10.1038/s41598-020-67274-1.
In this work, InGaN/GaN multiple-quantum-wells light-emitting diodes with and without graphene transparent conductive electrodes are studied with current-voltage, electroluminescence, and time-resolved electroluminescence (TREL) measurements. The results demonstrate that the applications of graphene electrodes on LED devices will spread injection carriers more uniformly into the active region and therefore result in a larger current density, broader luminescence area, and stronger EL intensity. In addition, the TREL data will be further analyzed by employing a 2-N theoretical model of carrier transport, capture, and escape processes. The combined experimental and theoretical results clearly indicate that those LEDs with graphene transparent conductive electrodes at p-junctions will have a shorter hole transport time along the lateral direction and thus a more efficient current spreading and a larger luminescence area. In addition, a shorter hole transport time will also expedite hole capture processes and result in a shorter capture time and better light emitting efficiency. Furthermore, as more carrier injected into the active regions of LEDs, thanks to graphene transparent conductive electrodes, excessive carriers need more time to proceed carrier recombination processes in QWs and result in a longer carrier recombination time. In short, the LED samples, with the help of graphene electrodes, are shown to have a better carrier transport efficiency, better carrier capture efficiency, and more electron-hole recombination. These research results provide important information for the carrier transport, carrier capture, and recombination processes in InGaN/GaN MQW LEDs with graphene transparent conductive electrodes.
在这项工作中,通过电流-电压、电致发光和时间分辨电致发光(TREL)测量,对有无石墨烯透明导电电极的氮化铟镓/氮化镓多量子阱发光二极管进行了研究。结果表明,在LED器件上应用石墨烯电极将使注入载流子更均匀地扩散到有源区,从而导致更大的电流密度、更宽的发光面积和更强的EL强度。此外,将采用载流子输运、捕获和逃逸过程的2-N理论模型对TREL数据进行进一步分析。实验和理论相结合的结果清楚地表明,在p结处带有石墨烯透明导电电极的那些LED,其空穴沿横向的输运时间会更短,从而具有更高效的电流扩散和更大的发光面积。此外,更短的空穴输运时间也将加速空穴捕获过程,导致更短的捕获时间和更好的发光效率。此外,由于石墨烯透明导电电极,当更多载流子注入到LED的有源区时,过量的载流子需要更多时间在量子阱中进行载流子复合过程,从而导致更长的载流子复合时间。简而言之,借助石墨烯电极的LED样品显示出具有更好的载流子输运效率、更好的载流子捕获效率和更多的电子-空穴复合。这些研究结果为具有石墨烯透明导电电极的氮化铟镓/氮化镓多量子阱发光二极管中的载流子输运、载流子捕获和复合过程提供了重要信息。