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蒸汽预处理对饮用水处理中通量恢复化学清洗中污染膜的影响。

Effects of steam pretreatment on fouled membrane in chemical cleaning for flux recovery in drinking water treatment.

机构信息

Department of Environmental Engineering, Daegu University, 201 Daegudae-ro, Jillyang, Gyeongsan-si, Gyeongbuk, 38453, Republic of Korea.

Graduate School of Water Resources, Sungkyunkwan University, 2066 Seobu-ro, Jangan-gu, Suwon, Gyeonggi-do, 440746, Republic of Korea.

出版信息

Environ Sci Pollut Res Int. 2020 Oct;27(28):35703-35711. doi: 10.1007/s11356-020-09831-9. Epub 2020 Jun 29.

Abstract

This paper shows the possibility of using steam pretreatment to improve the efficiency of membrane recovery chemical cleaning. Before applying chemicals to clean a fouled membrane, steam pretreatment was employed to loosen the structure of the foulant layer and weaken the attachment of those foulants on the membrane. Although longer steam contact times would lead to even better cleaning efficiency, the steam pretreatment duration was limited to less than 2 min to maintain membrane integrity. When cleaning fouled membranes with 1 mol/L HCl, the cleaning efficiency without steam pretreatment went from 83.3 to 90.2% as cleaning time increased from 30 to 180 min. As for 90-s steam pretreatment, the cleaning efficiency showed high values of more than 93% regardless of cleaning time. When the concentration of HCl was decreased to 0.2 mol/L, the cleaning efficiencies with a 90-s steam pretreatment was 78.6% and 92.6% for relatively short cleaning times of 30 and 60 min, respectively; this is much higher than the 62.2% and 76.7% achieved when cleaning without steam pretreatment. In addition, when using alkaline solution as the cleaning chemical, similar results were obtained. This implies that the application of steam before chemical cleaning is effective in improving cleaning efficiency, and so, this technique has the potential to reduce the amount of cleaning chemical required for membrane recovery cleaning.

摘要

本文展示了使用蒸汽预处理来提高膜回收化学清洗效率的可能性。在使用化学药品清洁污染膜之前,采用蒸汽预处理来松动污染物层的结构,并削弱污染物在膜上的附着。虽然更长的蒸汽接触时间会导致更好的清洗效果,但蒸汽预处理时间被限制在 2 分钟以内,以保持膜的完整性。当使用 1mol/L HCl 清洁污染膜时,在清洗时间从 30 分钟增加到 180 分钟时,未经蒸汽预处理的清洗效率从 83.3%提高到 90.2%。对于 90 秒的蒸汽预处理,无论清洗时间如何,清洗效率都表现出超过 93%的高值。当 HCl 浓度降低至 0.2mol/L 时,经过 90 秒蒸汽预处理的清洗效率分别为 78.6%和 92.6%,清洗时间较短,为 30 分钟和 60 分钟;这比未经蒸汽预处理的 62.2%和 76.7%高得多。此外,当使用碱性溶液作为清洗化学品时,也得到了类似的结果。这意味着在化学清洗之前使用蒸汽预处理是有效提高清洗效率的,因此,该技术有可能减少膜回收清洗所需的清洗化学品的用量。

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