Zhang Jie, Mei Ning, Liu Meng-Hao, Ye Xue-Song, Li Dong
Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing 100124, China.
State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China.
Huan Jing Ke Xue. 2020 Jun 8;41(6):2727-2735. doi: 10.13227/j.hjkx.201912111.
In a groundwater plant, removal of iron, manganese, and ammonia nitrogen was performed via a purification process using a filter column at a low temperature (5-6℃). Iron, manganese and ammonia [Fe(Ⅱ) 0-19.26 mg·L, Mn(Ⅱ) 0.52-2.05 mg·L, and NH-N 0.37-2.59 mg·L] were analyzed to explore the ammonia nitrogen removal efficiency under different iron and manganese concentrations. The results showed that when the concentration of manganese in the inlet water was maintained at approximately 0.6 mg·L and the concentration of ferrous iron in the inlet water was increased, with the increase of iron oxides in the filter layer, the ratio of ammonia nitrogen removed by adsorption of iron oxides increased, while the ratio of ammonia nitrogen removed by nitrification will decreased and adsorption preceded nitrification. When the concentration of ferrous iron in the water was maintained at approximately 8 mg·Land 11 mg·L, and the concentration of manganese in the water was increased, the proportion of ammonia nitrogen removed by adsorption did not increase with the increase of manganese oxide, and the removal route of ammonia nitrogen hardly changed. This is because less manganese oxides were formed 20 cm before the filter layer, which had little effect on the ammonia nitrogen adsorbed in this range. The production area of manganese oxides was concentrated below 20 cm of the filter layer, and most ammonia nitrogen was removed by adsorption and nitrification before this area, and the manganese oxides in this area did not adsorb ammonia nitrogen.
在一个地下水处理厂中,通过在低温(5 - 6℃)下使用过滤柱的净化工艺来去除铁、锰和氨氮。对铁、锰和氨(Fe(Ⅱ) 0 - 19.26 mg·L、Mn(Ⅱ) 0.52 - 2.05 mg·L和NH-N 0.37 - 2.59 mg·L)进行分析,以探究不同铁和锰浓度下的氨氮去除效率。结果表明,当进水锰浓度维持在约0.6 mg·L且进水亚铁浓度增加时,随着滤层中铁氧化物的增加,铁氧化物吸附去除氨氮的比例增加,而硝化作用去除氨氮的比例降低,且吸附作用先于硝化作用。当水中亚铁浓度维持在约8 mg·L和11 mg·L且水中锰浓度增加时,吸附去除氨氮的比例并未随氧化锰的增加而增加,氨氮的去除途径几乎没有变化。这是因为在滤层前20 cm处形成的氧化锰较少,对该范围内吸附的氨氮影响较小。氧化锰的生成区域集中在滤层20 cm以下,大部分氨氮在该区域之前通过吸附和硝化作用被去除,该区域的氧化锰不吸附氨氮。