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Ho/Yb共掺杂光热敏氟碲酸盐玻璃荧光粉中的光子量化

Photon quantification in Ho/Yb co-doped opto-thermal sensitive fluotellurite glass phosphor.

作者信息

Yang J X, Li D S, Li G, Pun E Y B, Lin H

出版信息

Appl Opt. 2020 Jul 1;59(19):5752-5763. doi: 10.1364/AO.396393.

DOI:10.1364/AO.396393
PMID:32609701
Abstract

Multi-photon-excited thermal-correlated green and red upconversion (UC) emissions have been quantified in / co-doped fluotellurite (BZLFT) glass phosphor under the 978 nm laser excitation. The temperature dependence of the fluorescence intensity ratio (FIR) originated from UC emissions bands centered at 550 nm and 661 nm has been verified in the range of 303-543 K. The net emission photon numbers of +→ and → transition emissions are up to 40.08×10 and 68.51×10 in the 0.4.-0.4. co-doped BZLFT case under the 6.95/ laser power density. Furthermore, the quantum yield (QY) and luminous flux are determined to be dependent on pumping power. When the excitation power increases 874 mW, the QY values for 550 nm and 661 nm emissions are as high as 0.94×10 and 1.60×10. In addition, the high photon producing efficiency is conducive to ensuring high feedback to thermosensitive performance. The temperature thermal sensor can be manipulated steadily in medium temperature range, and the relative sensitivity reaches 0.4 at 303 K, which is 1 order of magnitude larger than those in several rare-earth-doped materials. Efficient photon conversion ability and high temperature sensitivity indicate that the rare-earth-ion-doped fluotellurite material has a prospective application in the construction of optical temperature sensors based on the FIR technique allowing for self-referenced temperature determination.

摘要

在978 nm激光激发下,对共掺杂氟碲酸盐(BZLFT)玻璃荧光粉中的多光子激发热相关绿色和红色上转换(UC)发射进行了量化。在303 - 543 K范围内,验证了源于中心波长为550 nm和661 nm的UC发射带的荧光强度比(FIR)的温度依赖性。在6.95 /激光功率密度下,0.4.-0.4.共掺杂BZLFT情况下,+→和→跃迁发射的净发射光子数分别高达40.08×10和68.51×10。此外,量子产率(QY)和光通量被确定为依赖于泵浦功率。当激发功率增加到874 mW时,550 nm和661 nm发射的QY值分别高达0.94×10和1.60×10。此外,高光子产生效率有利于确保对热敏性能的高反馈。该温度热传感器在中温范围内可稳定操作,在303 K时相对灵敏度达到0.4,比几种稀土掺杂材料的灵敏度大1个数量级。高效的光子转换能力和高温灵敏度表明,稀土离子掺杂的氟碲酸盐材料在基于FIR技术的光学温度传感器构建中具有潜在应用,该技术可实现自参考温度测定。

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