Instituto Pluridisciplinar, Universidad Complutense de Madrid, Paseo de Juan XXIII, 1, 28040 Madrid, Spain.
Chem Soc Rev. 2020 Aug 7;49(15):5159-5177. doi: 10.1039/c9cs00735k. Epub 2020 Jul 6.
This tutorial review describes recent developments in carbon-nitrogen bond-forming reactions (amination, amidation, nitration and nitrosation) that involve the use of boronic acids and some of their derivatives as carbon-nucleophiles in the absence of transition-metals. Issues pertaining to reagents and mechanisms are discussed.
本教程综述介绍了近年来在无过渡金属参与的情况下，利用硼酸及其衍生物作为碳亲核试剂进行碳-氮键形成反应（胺化、酰胺化、硝化和亚硝化）的研究进展。讨论了与试剂和反应机制相关的问题。
