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对前哥伦布时期秘鲁木乃伊的多模态化学研究。

The multimodal chemical study of pre-Columbian Peruvian mummies.

作者信息

van Dalen Luna Pieter, Majchrzak Lukasz, Malek Kamilla, Kuncewicz Joanna, Miskowiec Pawel

机构信息

Universidad Nacional Mayor de San Marcos, Escuela de Arqueología, Calle Germán Amézaga No. 375 Puerta No. 3/Lima Cercado de Lima, Lima, Peru.

出版信息

Analyst. 2020 Aug 21;145(16):5670-5681. doi: 10.1039/d0an01017k. Epub 2020 Jul 10.

Abstract

In the pre-Hispanic Central Andes, the mummified bodies of ancestors stood as the basis for the social and cosmic order. However, the mummification techniques in that region are still poorly understood, as there have been surprisingly few archaeometric studies on their technical aspects. For that reason, we selected two mummies of the Chancay culture (900-1533 AD), on which to perform extensive chemical characterisation using a combination of molecular and elemental analysis and nanoscale imaging. The multimodal chemical study included the use of ATR FTIR, Raman spectroscopy, SEM-EDX, GC-MS and HPLC-MS techniques, and allowed the identification of a plethora of organic and inorganic substances present in their skin. Moreover, we were able to recognise different patterns of decomposition in each case. Data obtained during this study suggest that, in the last centuries before the Inca Empire conquered the Peruvian Central Coast, local societies treated some of their dead in a special manner, covering their bodies with balms composed of many substances. Some of these substances had anti-decay properties and could stop further decomposition of the skin.

摘要

在西班牙殖民前的安第斯中部地区,祖先的木乃伊是社会和宇宙秩序的基础。然而,该地区的木乃伊制作技术仍鲜为人知,因为令人惊讶的是,关于其技术方面的考古测量研究极少。因此,我们选择了两具昌凯文化(公元900 - 1533年)的木乃伊,运用分子和元素分析以及纳米级成像相结合的方法对其进行广泛的化学表征。多模态化学研究使用了衰减全反射傅里叶变换红外光谱(ATR FTIR)、拉曼光谱、扫描电子显微镜 - 能谱仪(SEM - EDX)、气相色谱 - 质谱联用仪(GC - MS)和高效液相色谱 - 质谱联用仪(HPLC - MS)技术,从而鉴定出其皮肤中存在的大量有机和无机物质。此外,我们还能够识别出每具木乃伊不同的分解模式。这项研究期间获得的数据表明,在印加帝国征服秘鲁中部海岸之前的最后几个世纪里,当地社会以一种特殊的方式处理部分死者,用由多种物质组成的香脂覆盖他们的尸体。其中一些物质具有防腐特性,可以阻止皮肤的进一步分解。

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