Enhanced adsorption properties of zirconium modified chitosan-zeolite nanocomposites for vanadium ion removal.

The novel hybrid adsorbents, which were composed of nanozeolite and nanochitosan (NZ@NCT) and nanozeolite-multi walled carbon nanotube and nanochitosan (CNZ@NCT) were produced by simple method. The adsorption capacity of synthesized nanocomposites towards vanadium (V) was compared with that of a clinoptilolite-nanochitosan nanocomposite (CPL@NCT) obtained from natural zeolite. Zirconium (Zr) was employed to modify prepared nanocomposites because Zr (IV) has a strong affinity towards oxyanions such as V. Zr-modified nanocomposites and their pristine nanocomposites were comparatively characterized by different techniques. Batch experiments were conducted to find out the influence of different experimental factors. The adsorption capacities of all prepared materials towards V ions decreased with temperature increasing from 298 to 348 K. The calculated values of the thermodynamic parameters ΔH and ΔG demonstrated that the adsorption was exothermic and spontaneous. The adsorption process was described by the Freundlich isotherm and pseudo-second order model. The V species loaded nanocomposites could be regenerated by 0.5 M HCl-1.0 M thiourea solution. The adsorption performance was not considerably influenced by the coexistence of the nickel ( Ni) but nitrate (NO) and sulfate (SO) revealed slightly greater negative effects. The as-prepared nanocomposites can be used in three adsorption cycles without specific changing its adsorption efficiency.