Martin Johannes, Eyselein Jonathan, Langer Jens, Elsen Holger, Harder Sjoerd
Friedrich-Alexander-Universität Erlangen-Nürnberg, Inorganic and Organometallic Chemistry, Erlangen, Bavaria, Germany.
Chem Commun (Camb). 2020 Aug 11;56(64):9178-9181. doi: 10.1039/d0cc04330c.
Two large decanuclear hydride clusters of the general formula Ae10H16[N(R)R']4·(PMDTA)2 (Ae = Ca, Sr) were isolated. Both derivatives feature a [Ae10H16]4+ core, consisting of two edge shared metal octahedra with interstitial hydrides, while the other hydrides cap triangular faces.
分离出了通式为Ae10H16[N(R)R']4·(PMDTA)2（Ae = Ca，Sr）的两个大型十核氢化物簇。两种衍生物均具有[Ae10H16]4+核心，该核心由两个共用边的含间隙氢化物的金属八面体组成，而其他氢化物覆盖三角形面。
