Synthesis of Superconducting Cobalt Trihydride.

The Co-H system has been investigated through high-pressure, high-temperature X-ray diffraction experiments combined with first-principles calculations. On compression of elemental cobalt in a hydrogen medium, we observe face-centered cubic cobalt hydride (CoH) and cobalt dihydride (CoH) above 33 GPa. Laser heating CoH in a hydrogen matrix at 75 GPa to temperatures in excess of ∼800 K produces cobalt trihydride (CoH) which adopts a primitive structure. Density functional theory calculations support the stability of CoH. This phase is predicted to be thermodynamically stable at pressures above 18 GPa and to be a superconductor below 23 K. Theory predicts that this phase remains dynamically stable upon decompression above 11 GPa where it has a maximum of 30 K.