碘介导的电化学 C(sp 2 )-H 胺化反应：吲哚啉和吲哚的可切换合成。
Iodine-Mediated Electrochemical C(sp)-H Amination: Switchable Synthesis of Indolines and Indoles.
机构信息
University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.
Hefei National Laboratory for Physical Science at Microscale, CAS Key Laboratory of Soft Matter Chemistry & Center for Excellence in Molecular Synthesis of Chinese Academy of Science, Collaborative Innovation Center of Suzhou Nano Science and Technology & School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.
出版信息
Org Lett. 2020 Aug 7;22(15):5773-5777. doi: 10.1021/acs.orglett.0c01821. Epub 2020 Jul 14.
A metal-free electrochemical intramolecular C(sp)-H amination using iodine as a mediator was developed. This method enables a switchable synthesis of indoline and indole derivatives, respectively, from easily available 2-vinyl anilines.
发展了一种无金属的电化学分子内 C(sp 3 )-H 胺化反应，使用碘作为介体。该方法可以从易得的 2-乙烯基苯胺分别选择性合成吲哚啉和吲哚衍生物。
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