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用于高性能不对称超级电容器的双金属铁镍衍生的NiFeO@Ni-Mn LDH复合电极材料。

Bimetallic FeNi-MIL-88-derived NiFeO@Ni-Mn LDH composite electrode material for a high performance asymmetric supercapacitor.

作者信息

Li Shaobin, Pan Jing, Li Fengbo, Zhang Li, Chai Dongfeng, Zhang Zhuanfang, Xin Jianjiao

机构信息

College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006, China.

出版信息

Dalton Trans. 2020 Aug 7;49(29):10203-10211. doi: 10.1039/d0dt00251h. Epub 2020 Jul 15.

DOI:10.1039/d0dt00251h
PMID:32666972
Abstract

A simple continuous hydrothermal method was used to synthesize a NiFeO@Ni-Mn LDH/NF composite. The layered structure provides a large void to transfer the electron effectively, and the composite materials exhibit remarkable electrochemical performance including excellent specific capacitance (1265 F g at 1 A g) and remarkable cycling stability (the specific capacitance remains at 80.9% after 5000 cycles). In addition, the asymmetric supercapacitor exhibits a high energy density of 96.2 W h kg at a power density of 700 W kg, and there is an extraordinarily good cycling stability with a capacity retention rate of 92.5% after 4000 cycles. The outcomes indicate that the NiFeO@Ni-Mn LDH/NF composite electrode has potential application as a high-performance supercapacitor.

摘要

采用一种简单的连续水热法合成了NiFeO@Ni-Mn LDH/NF复合材料。层状结构提供了大的空隙以有效地传输电子,并且该复合材料表现出显著的电化学性能,包括优异的比电容(在1 A g下为1265 F g)和显著的循环稳定性(5000次循环后比电容保持在80.9%)。此外,不对称超级电容器在功率密度为700 W kg时表现出96.2 W h kg的高能量密度,并且具有非常好的循环稳定性,4000次循环后的容量保持率为92.5%。结果表明,NiFeO@Ni-Mn LDH/NF复合电极作为高性能超级电容器具有潜在的应用价值。

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