Fast and effective recovery of Au(III) from aqueous solution by a N-containing polymer.

In this work, a N-containing polymer was successfully synthesized by one-step treatment with 3-amine-1,2,4-triazole ligands and Zn(II) using the thermal solvent method, and employed to recover Au(III) from water. The adsorption kinetics was comprehensively studied through kinetics models including pseudo-first-order model, pseudo-second-order model, moving boundary model and Weber-Morris model. It is found that the overall adsorption rate was determined by chemical adsorption, and the rate-limiting step of diffusion steps is film diffusion. Rising temperature can improve the adsorption rate significantly, making the adsorption equilibrium time be reduced from 6 h at 298 K to 2 h at 318 K. The adsorption isotherm can be described well by Sips model, indicating it is a heterogeneous adsorption. The material shows high adsorption capacity towards Au(III) up to 1073 mg/g. It shows strong affinity towards Au(III) in the mixture solutions containing Au(III), Cu(II), Zn(II), Co(II), Cd(II), Pb(II) and Ni(II) ions. The material can be easily and completely desorbed by thiourea solution and still maintains its adsorption performance only with a slight decrease after three cycles. Combined with studies on pH influence, adsorption kinetics, adsorption isotherm and XPS analysis, it can be concluded that the adsorption mechanism could be attributed to electrostatic interaction, the coordination of the Zn-OH and -C-N/-CN- with Au(III), and partial reduction of Au(III) to Au(I) by -NH group on the polymer. The N-containing polymer is an excellent candidate for Au(III) recovery efficiently and selectively from aqueous solution.