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从晶体结构角度看氦在元素周期表中的位置。

Helium's placement in the Periodic Table from a crystal structure viewpoint.

作者信息

Kurushkin Mikhail

机构信息

Chemistry Education Research and Practice Laboratory, SCAMT Institute, ITMO University, 9 Lomonosova Str., Saint Petersburg, Saint Petersburg 191002, Russian Federation.

出版信息

IUCrJ. 2020 Jun 13;7(Pt 4):577-578. doi: 10.1107/S2052252520007769. eCollection 2020 Jul 1.

DOI:10.1107/S2052252520007769
PMID:32695406
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7340260/
Abstract

The present paper indicates that helium has more in common with the alkaline earths than is often considered. Not only does it share an analogous electron configuration but it also has an analogous crystal structure to that of beryllium and magnesium which is, in contrast, characteristic of the bulk material rather than of isolated atoms.

摘要

本文指出,氦与碱土金属的共性比通常认为的更多。它不仅具有类似的电子构型,而且其晶体结构与铍和镁的晶体结构类似,相比之下,这是大块材料而非孤立原子的特征。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3858/7340260/a816e38c2179/m-07-00577-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3858/7340260/a816e38c2179/m-07-00577-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3858/7340260/a816e38c2179/m-07-00577-fig1.jpg

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Can quantum ideas explain chemistry's greatest icon?量子概念能解释化学界最伟大的标志吗?
Nature. 2019 Jan;565(7741):557-559. doi: 10.1038/d41586-019-00286-8.
3
Rare Helium-Bearing Compound FeO_{2}He Stabilized at Deep-Earth Conditions.深地条件下稳定存在的富含氦的罕见化合物 FeO_{2}He
Phys Rev Lett. 2018 Dec 21;121(25):255703. doi: 10.1103/PhysRevLett.121.255703.
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Helium-Iron Compounds at Terapascal Pressures.氦-铁化合物在太帕斯卡压力下。
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A stable compound of helium and sodium at high pressure.高压下氦和钠的稳定化合物。
Nat Chem. 2017 May;9(5):440-445. doi: 10.1038/nchem.2716. Epub 2017 Feb 6.