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新型羟基磷酸盐SrCo(OH)(PO)的晶体结构

Crystal structure of SrCo(OH)(PO), a new hy-droxy-phosphate.

作者信息

Cherif Fatima-Zahra, Taibi Mhamed, Boukhari Ali, Aride Jilali, Assani Abderrazzak, Saadi Mohamed, El Ammari Lahcen

机构信息

Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Science, Mohammed V University in Rabat, Avenue Ibn Batouta, BP 1014, Rabat, Morocco.

Laboratoire de Physico-Chimie des Matériaux Inorganiques et Organiques, Centre des Sciences des Matériaux, Ecole Normale Supérieure, Mohammed V University in Rabat, Morocco.

出版信息

Acta Crystallogr E Crystallogr Commun. 2020 Jun 5;76(Pt 7):1022-1026. doi: 10.1107/S2056989020007331. eCollection 2020 Jul 1.

DOI:10.1107/S2056989020007331
PMID:32695445
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7336777/
Abstract

Single crystals of strontium tetra-cobalt tris-(orthophosphate) hydroxide, SrCo(OH)(PO), were grown serendipitously under hydro-thermal conditions at 473 K. The crystal structure consists of undulating chains of edge-sharing [CoO] octa-hedra that are linked into (010) layers by common vertices between chains. Adjacent layers are linked along [010] into a framework structure by tetra-hedral [CoO] units and by PO tetra-hedra. The framework delimits channels extending along [100] in which the eleven-coordinate strontium cations are situated. Bifurcated O-H⋯O hydrogen bonds of weak strengths consolidate the crystal packing. The title compound was also characterized by infrared spectroscopy.

摘要

四钴三（正磷酸）氢氧化锶单晶，即SrCo(OH)(PO)，在473 K的水热条件下意外生长而成。晶体结构由共享边的[CoO]八面体的起伏链组成，这些链通过链间的公共顶点连接成(010)层。相邻层通过四面体[CoO]单元和PO四面体沿[010]连接成框架结构。该框架界定了沿[100]延伸的通道，十一配位的锶阳离子位于其中。强度较弱的分叉O-H⋯O氢键巩固了晶体堆积。该标题化合物还通过红外光谱进行了表征。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d14a/7336777/6a7c9b69a701/e-76-01022-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d14a/7336777/c876744244b0/e-76-01022-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d14a/7336777/ccaa1086b847/e-76-01022-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d14a/7336777/1f39af3dd11d/e-76-01022-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d14a/7336777/ee394f8b0685/e-76-01022-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d14a/7336777/ca6035ca9311/e-76-01022-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d14a/7336777/6a7c9b69a701/e-76-01022-fig6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d14a/7336777/c876744244b0/e-76-01022-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d14a/7336777/ccaa1086b847/e-76-01022-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d14a/7336777/1f39af3dd11d/e-76-01022-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d14a/7336777/ee394f8b0685/e-76-01022-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d14a/7336777/ca6035ca9311/e-76-01022-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d14a/7336777/6a7c9b69a701/e-76-01022-fig6.jpg

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