[二氯金（II）-N，N-双（2-羟乙基）二硫代氨基甲酸酯-S，S']
[N,N-bis(2-hydroxyethyl)dithiocarbamato-S,S']dichlorogold( II).
作者信息
Lock C J, Turner M A, Parish R V, Potter G
机构信息
Department of Chemistry, McMaster University, Hamilton, ON, Canada.
出版信息
Acta Crystallogr C. 1988 Dec 15;44 ( Pt 12):2082-5. doi: 10.1107/s0108270188008662.
[Au(C5H10NO2S2)Cl2], Mr = 448.1, space group P212121 (No. 19), a = 7.446 (2), b = 11.434 (4), c = 13.110 (3) A, V = 1116.2 (5) A3, Z = 4, Dm = 2.74 (5), Dx = 2.67 g cm 3, graphite-monochromatized Mo Ka radiation, lambda = 0.71069 A, mu = 144.0 cm-1, F(000) = 832.2, T = 298 K, R = 0.0432, wR = 0.0397 for 1974 unique reflections and 118 parameters. The gold atom is in a roughly squareplanar environment, distorted as a result of the small bite distance of the chelating dithiocarbamate ligand. Molecules pack in the crystal lattice such that there are linear...S...Au...S... chains parallel to the a axis.
[二氯（二硫代氨基甲酸 - 2 - 氨基 - 2 - 甲基 - 1 - 丙醇）金（I）]，Mr = 448.1，空间群P212121（编号19），a = 7.446（2），b = 11.434（4），c = 13.110（3）Å，V = 1116.2（5）ų，Z = 4，Dm = 2.74（5），Dx = 2.67 g/cm³，石墨单色器的钼Kα辐射，λ = 0.71069 Å，μ = 144.0 cm⁻¹，F(000) = 832.2，T = 298 K，对于1974个独立反射和118个参数，R = 0.0432，wR = 0.0397。金原子处于大致的平面正方形环境中，由于螯合二硫代氨基甲酸盐配体的小咬合距离而发生扭曲。分子在晶格中堆积，使得存在平行于a轴的线性...S...Au...S...链。
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