Non-Linear Optical Properties of Er-Yb-Doped NaGdF Nanostructured Glass-Ceramics.

Transparent oxyfluoride glass-ceramics containing NaGdF nanocrystals were prepared by melt-quenching and doped with Er (0.5 mol%) and different amounts of Yb (0-2 mol%). The selected dopant concentration the crystallization thermal treatments were chosen to obtain the most efficient visible up-conversion emissions, together with near infrared emissions. The crystal size increased with dopant content and treatment time. NaGdF NCs with a size ranging 9-30 nm were obtained after heat treatments at T + 20-80 °C as confirmed by X-ray diffraction and high-resolution transmission electron microscopy. Energy dispersive X-ray analysis shows the incorporation of rare earth ions into the NaGdF nanocrystals. Near-infrared emission spectra, together with the up-conversion emissions were measured. The optical characterization of the glass-ceramics clearly shows that Er and Yb ions are incorporated in the crystalline phase. Moreover, visible up-conversion emissions could be tuned by controlling the nanocrystals size through appropriated heat treatment, making possible a correlation between structural and optical properties.