Parvez M, Napper A D, Benkovic S J
Department of Chemistry, Pennsylvania State University, University Park 16802.
Acta Crystallogr C. 1988 Aug 15;44 ( Pt 8):1414-6. doi: 10.1107/s0108270188003324.
C11H14IO3P, Mr = 352.11, monoclinic, P2(1)/n, a = 8.300 (3), b = 14.081 (2), c = 11.326 (4) A, beta = 104.32 (3) degrees, V = 1282.6 (13) A3, Z = 4, D chi = 1.823 Mg m-3, lambda(Mo K alpha) = 0.71073 A, mu = 25.8 cm-1, F(000) = 688, R = 0.035 for 2364 observed reflections. The six-membered ring O(1), P(2), C(3), C(4), C(5), C(6) is in a chair conformation with phenoxy and iodomethyl groups adopting axial and equatorial orientations, respectively. The bond distances and angles are unexceptional.
C11H14IO3P，Mr = 352.11，单斜晶系，P2(1)/n，a = 8.300(3)，b = 14.081(2)，c = 11.326(4)埃，β = 104.32(3)°，V = 1282.6(13)埃³，Z = 4，Dχ = 1.823 Mg m⁻³，λ(Mo Kα) = 0.71073埃，μ = 25.8 cm⁻¹，F(000) = 688，对于2364个观测反射，R = 0.035。六元环O(1)、P(2)、C(3)、C(4)、C(5)、C(6)呈椅式构象，苯氧基和碘甲基分别采取轴向和赤道取向。键长和键角无异常。
