Krishnamurthy K S, Rao D S Shankar, Kanakala Madhu B, Yelamaggad Channabasaveshwar V, Kleman Maurice
Centre for Nano and Soft Matter Sciences, P. O. Box 1329, Jalahalli, Bangalore 560013, India.
Institut de physique du globe de Paris, Université de Paris, 1, rue Jussieu, 75238, Paris Cedex 05, France.
Soft Matter. 2020 Aug 19;16(32):7479-7491. doi: 10.1039/d0sm01085e.
Colloids formed of solid/fluid particle dispersions in oriented nematic liquid crystals are known to be an ideal means of realizing fundamentally significant topological defect geometries. We find, experimentally, that twist-bend nematic (NTB) droplets formed in the N-NTB biphasic regime, either of pure compounds or mesogenic mixtures, completely mimic colloidal particles in their ability to generate a rich variety of defects. In the biphasic regime, the topological features of both liquid crystal colloids and chiral nematic droplets are revealed by (i) topological dipoles, quadrupoles and their patterned clusters formed in planar nematic liquid crystals orientationally perturbed by coexisting NTB drops, (ii) the transformation of hyperbolic hedgehogs into knotted Saturn rings encircling the NTB drops dispersed in a 90°-twisted nematic matrix and (iii) the Frank-Pryce defect texture evident in smaller (relative to sample thickness) NTB drops. In larger drops with fingerlike outgrowths, additional line defects appear; most of these are deemed to be pairs of disclinations to which are attached pairs of screw dislocations intervening in the growth process of the NTB droplets.
由固体/流体颗粒分散在向列型液晶中形成的胶体被认为是实现具有根本重要性的拓扑缺陷几何结构的理想手段。我们通过实验发现,在N-NTB双相体系中形成的扭曲弯曲向列相(NTB)液滴,无论是纯化合物还是介晶混合物,在产生丰富多样的缺陷方面完全模仿了胶体颗粒。在双相体系中,液晶胶体和手性向列相液滴的拓扑特征通过以下方式得以揭示:(i)在由共存的NTB液滴定向扰动的平面向列型液晶中形成的拓扑偶极子、四极子及其图案化簇;(ii)双曲刺猬转变为环绕分散在90°扭曲向列相基质中的NTB液滴的打结土星环;(iii)在较小(相对于样品厚度)的NTB液滴中明显的弗兰克-普赖斯缺陷纹理。在具有指状突出物的较大液滴中,会出现额外的线缺陷;其中大多数被认为是成对的位错,在NTB液滴的生长过程中,成对的螺旋位错附着在这些位错上。