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含杯[4]吡咯衍生物聚合物膜对硝酸根溶液中银（I）的选择传输。

Selective Transport of Ag(I) through a Polymer Inclusion Membrane Containing a Calix[4]pyrrole Derivative from Nitrate Aqueous Solutions.

机构信息

Institute of Chemistry, Jan Dlugosz University of Czestochowa, PL42200 Czestochowa, Poland.

出版信息

Int J Mol Sci. 2020 Jul 28;21(15):5348. doi: 10.3390/ijms21155348.

DOI:10.3390/ijms21155348
PMID:32731385
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7432600/
Abstract

Cellulose-triacetate-based polymer inclusion membranes (PIMs) with different concentrations of a calixpyrrole ester derivative as the membrane carrier were studied to determine their ability to transport Ag(I) from aqueous nitrate solutions. The effects of the concentrations of ion carriers and metal ions, the pH of the source aqueous phase, and stripping agents on the effective transport of Ag(I) were assessed. All studied parameters were found to be important factors for the transport of Ag(I) metal ions. The initial fluxes were determined at different temperatures. The prepared membranes were found to be highly permeable. The selectivity of silver transport from an aqueous solution containing Ag(I), Cu(II), Pb(II), Cd(II), Ni(II), Zn(II), and Co(II) ions was also investigated.

摘要

以不同浓度的杯吡咯酯衍生物作为膜载体的纤维素三醋酸酯基聚合物渗透膜（PIM）被研究，以确定它们从硝酸水溶液中输送银（I）的能力。评估了离子载体和金属离子浓度、源水相 pH 值以及剥离剂对 Ag（I）有效输送的影响。所有研究的参数都被发现是 Ag（I）金属离子输送的重要因素。在不同温度下测定了初始通量。发现所制备的膜具有高渗透性。还研究了从含有 Ag（I）、Cu（II）、Pb（II）、Cd（II）、Ni（II）、Zn（II）和 Co（II）离子的水溶液中选择性输送银的情况。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/36700df369f7/ijms-21-05348-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/1a06285bddc8/ijms-21-05348-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/3313998af414/ijms-21-05348-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/b3e4342c6096/ijms-21-05348-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/40468d4f8275/ijms-21-05348-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/551032e0efcc/ijms-21-05348-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/8744c5de4c4f/ijms-21-05348-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/d663bba3f6d7/ijms-21-05348-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/a2e81fb18c90/ijms-21-05348-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/36700df369f7/ijms-21-05348-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/1a06285bddc8/ijms-21-05348-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/3313998af414/ijms-21-05348-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/b3e4342c6096/ijms-21-05348-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/40468d4f8275/ijms-21-05348-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/551032e0efcc/ijms-21-05348-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/8744c5de4c4f/ijms-21-05348-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/d663bba3f6d7/ijms-21-05348-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/a2e81fb18c90/ijms-21-05348-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/18da/7432600/36700df369f7/ijms-21-05348-g009.jpg

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