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主族金属茂桥环化合物

Main-Group Metallocenophanes.

作者信息

Wirtz Lisa, Schäfer André

机构信息

Faculty of Natural Science and Technology, Department of Chemistry, Saarland University, Campus Saarbrücken, 66123, Saarbrücken, Germany.

出版信息

Chemistry. 2021 Jan 18;27(4):1219-1230. doi: 10.1002/chem.202003161. Epub 2020 Oct 28.

DOI:10.1002/chem.202003161
PMID:32735356
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7894164/
Abstract

Metallocenes with interlinked cyclopentadienide ligands are commonly referred to as ansa-metallocenes or metallocenophanes. These can have drastically different properties than their unbridged parent compounds. While this concept is best known for transition metals such as iron, it can also be adopted for many main-group elements. This review aims to summarize recent advances in the field of metallocenophanes based on main-group elements of group 2, group 13, group 14 and group 15, focusing on synthesis, structure and properties of these compounds.

摘要

具有相互连接的环戊二烯基配体的金属茂通常被称为桥连金属茂或茂金属环。它们的性质可能与其非桥连母体化合物有很大不同。虽然这个概念在铁等过渡金属中最为人所知，但它也可用于许多主族元素。本综述旨在总结基于第2族、第13族、第14族和第15族主族元素的茂金属环领域的最新进展，重点关注这些化合物的合成、结构和性质。

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