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聚集诱导发光-固态中的发光锡化合物。

Aggregation induced emission - emissive stannoles in the solid state.

机构信息

University of Bremen, Institute for Organic and Analytical Chemistry, Leobener Str. 7, 28359 Bremen, Germany.

University of Bremen, Institute for Applied and Physical Chemistry, Leobener Str. 5, 28359 Bremen, Germany.

出版信息

Chem Commun (Camb). 2020 Aug 25;56(68):9775-9778. doi: 10.1039/d0cc04525j.

DOI:10.1039/d0cc04525j
PMID:32748898
Abstract

The optoelectronic and structural properties of six stannoles are reported. All revealed extremely weak emission in solution at 295 K, but intensive fluorescence in the solid state with quantum yields (ΦF) of up to 11.1% in the crystal, and of up to 24.4% (ΦF) in the thin film.

摘要

报告了六种锡烷的光电和结构性质。所有锡烷在 295 K 下的溶液中都显示出非常微弱的发射,但在固态下具有强烈的荧光,其量子产率(ΦF)在晶体中高达 11.1%,在薄膜中高达 24.4%(ΦF)。

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