Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Ondo State, Nigeria.
Department of Chemistry, Ekiti State University, Ado-Ekiti, Nigeria.
Crit Rev Food Sci Nutr. 2021;61(17):2938-2959. doi: 10.1080/10408398.2020.1791048. Epub 2020 Aug 6.
The purpose of this write-up is to discuss the recent developments in the study of the physicochemical and functional properties of legume starches. Legumes are abundantly rich in proteins, polysaccharides, vitamins, and minerals. Starch is the most important polysaccharide in the human diet. The amylose, lipid, ash, and nitrogen content of legume starches vary in the range of 18-52%, 0.1-0.9, 0.0-0.7%, and 0.0-0.3%, respectively. The legume starches are characteristically rich in amylose, display limited swelling power, poor dispersibility in water, and vulnerable to retrogradation. The properties of legume starches reveal that they possess strong bonding chains between its molecules. Due to these strong bonds, legume starches have high gelatinization transition temperatures and enthalpies. Furthermore, the pasting properties are in accordance with this concept. Legume starches differ in granule morphology, gelatinization transition temperatures, and amylose content. There is need for modification of legume starches due to poor functionality such as easy vulnerability to retrogradation and poor processing properties when subjected to extreme of conditions. These shortcomings of legume starches are usually mitigated by annealing, heat-moisture treatment, cross-linking, acid-thinning, oxidation, and acetylation. This review highlighted developments in the isolation, composition, morphology, physicochemical properties, and some aspect of physical and chemical modification of legume starches.
本文旨在讨论豆类淀粉理化功能特性研究的最新进展。豆类富含蛋白质、多糖、维生素和矿物质。淀粉是人类饮食中最重要的多糖。豆类淀粉的直链淀粉、脂质、灰分和氮含量分别在 18-52%、0.1-0.9%、0.0-0.7%和 0.0-0.3%的范围内变化。豆类淀粉的直链淀粉含量特别丰富,膨胀能力有限,在水中的分散性差,易发生回生。豆类淀粉的特性表明其分子间具有较强的结合链。由于这些强键,豆类淀粉具有较高的胶凝化转变温度和焓。此外,糊化特性也符合这一概念。豆类淀粉在颗粒形态、胶凝化转变温度和直链淀粉含量方面存在差异。由于功能较差,如易回生和在极端条件下加工性能差,需要对豆类淀粉进行改性。通过退火、湿热处理、交联、酸处理、氧化和乙酰化可以减轻豆类淀粉的这些缺点。本综述重点介绍了豆类淀粉的分离、组成、形态、理化性质以及物理化学改性的一些方面的进展。