Zappe Lisa, Schönfeld Sophie, Hörner Gerald, Zenere Katrina A, Leong Chanel F, Kepert Cameron J, D'Alessandro Deanna M, Weber Birgit, Neville Suzanne M
Department of Chemistry, University of Bayreuth, Universitätsstraße 30, 95448 Bayreuth, Germany.
Chem Commun (Camb). 2020 Sep 16;56(72):10469-10472. doi: 10.1039/d0cc03788e. Epub 2020 Aug 7.
A one-dimensional Fe coordination polymer (CP) has been formed which includes the redox-active ligand bis-pyridyltetrathiafulvalene (pyTTF) and a Schiff base-like NO ligand. This CP is both spin crossover (SCO) and redox-active in the solid-state, and chemical oxidation results in SCO modification.
一种一维铁配位聚合物（CP）已经形成，它包含氧化还原活性配体双吡啶四硫富瓦烯（pyTTF）和一种席夫碱类NO配体。这种CP在固态下兼具自旋交叉（SCO）和氧化还原活性，化学氧化会导致SCO改性。
