Search for effective eluent for Pd separation on ion-exchange sorbent before voltammetric determination.

Determination of Pd traces in environmental samples is still a challenging analytical task. The aim of this study was to propose an efficient system (i.e. ion-exchange resin and eluent) for Pd elution from SPE column after the analyte preconcentration. Moreover, the search was focused on solvents that would not interfere voltammetric determination of Pd, as well as ICP-MS analysis. Five ion-exchange sorbents were compared in terms of effective Pd separation from matrix components when using different eluents. The highest recovery (up to 91%) of palladium was obtained for Dowex 1 and ammonium buffer as the eluent. This solution not only provides relatively high palladium elution efficiency but also allows both voltammetric and ICP-MS determinations, without any additional sample preparation. It was proven that the proposed procedure including SPE separation and determination with AdSV and/or ICP-MS could be used for quantitative Pd measurement in environmental samples, such as quartz sand used for the monitoring of Pd emission in the areas of high traffic density.