构建和控制用于乙炔氯化的钌活性相。
Constructing and controlling ruthenium active phases for acetylene hydrochlorination.
机构信息
Industrial Catalysis Institute of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Hangzhou, 310014, P. R. China.
出版信息
Chem Commun (Camb). 2020 Sep 15;56(73):10722-10725. doi: 10.1039/d0cc04382f.
PMID:32789339
Abstract
Ru-Based catalysts with distinct active phases from Ru0, to RuO2, RuCl3 and RuCl2N were synthesized and evaluated in acetylene hydrochlorination. RuCl2N is identified as the efficient active phase due to its co-activation of acetylene and hydrogen chloride. This discovery holds great potential to accelerate the large-scale application of Ru-based catalysts in industry.
摘要
合成了具有不同于 Ru0、RuO2、RuCl3 和 RuCl2N 的活性相的 Ru 基催化剂，并在乙炔氯化中进行了评价。RuCl2N 被确定为有效的活性相，因为它能协同活化乙炔和氯化氢。这一发现有望加速 Ru 基催化剂在工业中的大规模应用。
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