控制Ru(II)/Re(I)二元体系中CO的光催化还原 连接体氧化态
Controlling photocatalytic reduction of CO in Ru(II)/Re(I) dyads linker oxidation state.
作者信息
Brown Christopher M, Auvray Thomas, DeLuca Emile E, Ezhova Maria B, Hanan Garry S, Wolf Michael O
机构信息
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC V6T 1Z1, Canada.
出版信息
Chem Commun (Camb). 2020 Sep 15;56(73):10750-10753. doi: 10.1039/d0cc04597g.
PMID:32789403
Abstract
Electronic communication between the linked metal centers in Ru(ii)-Re(i) dyads is tuned using the oxidation state (S and SO2) of sulfur-bridged ligands. Higher catalytic activity is seen for the SO2-bridged dyad in the photocatalytic reduction of CO2.
摘要
通过硫桥连配体的氧化态（S和SO₂）来调节Ru（II）-Re（I）二元体系中相连金属中心之间的电子通信。在光催化还原CO₂过程中，SO₂桥连的二元体系表现出更高的催化活性。
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