In situ monitoring of catalytic reaction on single nanoporous gold nanowire with tuneable SERS and catalytic activity.

Single nanoporous gold nanowire was introduced as a tunable one-dimensional nano-sensor platform with both SERS and catalytic activity, and it precisely fit the requirement of materials for in situ SERS monitoring of plasmon-assisted catalytic reaction. The nanoporous gold nanowires exhibited much more "hot spots" on their surface and much better SPR effect than the smooth nanowires. We demonstrated that these nanowires could be used as a SERS substrate assuring the sensitivity and reproducibility of Raman signals. Besides, they could be applied as a kind of heterogeneous catalyst for in situ SERS monitoring of the plasmon-assisted catalytic reaction-reduction of p-nitrothiophenol (p-NTP) to p,p-dimercaptoazobenzene (DMAB) at their surface. The SERS and catalytic activity of the nanowires could be respectively optimized by adjusting their dealloying time, similar to the procedure of catalyst screening.