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用于增强锂存储的废弃生物质衍生碳阳极

Waste Biomass-Derived Carbon Anode for Enhanced Lithium Storage.

作者信息

Yokokura Takashi J, Rodriguez Jassiel R, Pol Vilas G

机构信息

Davidson School of Chemical Engineering, Purdue University, 480 W Stadium Avenue, West Lafayette, Indiana 47907, United States.

出版信息

ACS Omega. 2020 Aug 3;5(31):19715-19720. doi: 10.1021/acsomega.0c02389. eCollection 2020 Aug 11.

Abstract

Due to increased populations, there is an increased demand for food; thus, battery electrode materials created from waste biomass provide an attractive opportunity. Unfortunately, such batteries rarely sustain capacities comparable to current state-of-the-art technologies. However, an anode synthesized from waste avocado seeds provides high cycling stability over 100 cycles and provides comparable capacity to graphite, around 315 mAh g at 100 mA g current density, and readily outperforms graphene in terms of both stability and capacity. This novel electrode provides such capacities as an amorphous carbon without the use of any additives or doped heteroatoms by utilizing capacitance-driven mechanisms to contribute to 54% of its lithium-ion storage. This allows the waste biomass-derived anode to overcome its low apparent diffusion coefficient of 4.38 × 10 cm s. By creating battery anodes from avocado seeds, waste streams can be redirected into creating valuable, renewable energy storage resources.

摘要

由于人口增长,对食物的需求也在增加;因此,由废弃生物质制成的电池电极材料提供了一个有吸引力的机会。不幸的是,这类电池的容量很少能与当前的先进技术相媲美。然而,由废弃鳄梨种子合成的阳极在100次循环中具有高循环稳定性,并且在100 mA g电流密度下提供与石墨相当的容量,约为315 mAh g,并且在稳定性和容量方面均优于石墨烯。这种新型电极通过利用电容驱动机制贡献其54%的锂离子存储,从而在不使用任何添加剂或掺杂杂原子的情况下提供了如非晶碳般的容量。这使得源自废弃生物质的阳极能够克服其4.38×10 cm s的低表观扩散系数。通过用鳄梨种子制造电池阳极,废物流可以被重新导向创造有价值的可再生能源存储资源。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7faf/7424741/76f3ca446063/ao0c02389_0002.jpg

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