Insight into efficient removal of Cr(VI) by magnetite immobilized with Lysinibacillus sp. JLT12: Mechanism and performance.

In this work, Lysinibacillus sp. JLT12 was used to remove the Cr(VI)-induced passive layer on the magnetite. Mechanism study via dynamic kinetics, X-ray diffraction, Raman spectroscopy, and X-ray photoelectron spectroscopy analyses revealed that Lysinibacillus sp. JLT12 could remove the passive layer (lepidocrocite and goethite) to facilitate the further Cr(VI) reduction by magnetite. For large-scale applications, porous ceramsite (PC) was prepared with magnetite, kaolin, and fallen leaves. Lysinibacillus sp. was then immobilized on the holes in PC. Slow-released nutrients were added to immobilized porous ceramsite (IM-PC) at a ratio of 1.5:10 (g/g) to supply carbon, nitrogen, and phosphorus to Lysinibacillus sp. JLT12 with low secondary pollution. The performance of IM-PC was evaluated via a column experiment. The results indicate that, in the presence of Lysinibacillus, the break-through time and maximum adsorption ability of IM-PC were 11.67 h and 121.47 mg/g, respectively. These values are higher than those of PC. Additionally, break-through curves detected at 5, 10, and 15 days demonstrated that the usage life of IM-PC was significantly longer than that of PC.