Inorganic Molecular Clusters with Facile Preparation and Neutral pH for Efficient Hole Extraction in Organic Solar Cells.

The development of electrode interlayers for hole extraction is a great challenge in the field of organic solar cells (OSCs). At present, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is the only solution-processed anode interlayer (AIL) that can be used to achieve power conversion efficiencies (PCEs) over 15% in OSC devices, even though there are several well-known drawbacks in practical applications of PEDOT:PSS. Herein, we use an inorganic molecular cluster (IMC) as the AIL for making highly efficient and large-area OSCs. The IMC possesses several advantages in serving as the AIL, such as neutral pH, excellent optical transmittance, high work function, good film-forming properties, and low cost. OSCs using the IMC can achieve a high PCE of 13.38%, which is superior to the PCE of the PEDOT:PSS device. This is among the few examples of OSC devices with solution-processed and pH neutral AILs showing higher PCE than PEDOT:PSS devices. Ultraviolet photoelectron spectroscopy and electron spin resonance results indicate the formation of inorganic-organic heterojunction, which is crucial for efficient hole extraction. More importantly, the IMC is compatible with printing processing. Using a blade-coated IMC film, we fabricated a large-area OSC of 1 cm and a high PCE of 9.5% was achieved.