Investigation on Spontaneous Shape Change of 4D Printed Starch-Based Purees from Purple Sweet Potatoes As Induced by Microwave Dehydration.

The time evolution of three-dimensional (3D) printed food structures as affected by their composition and postprinting stimulus is an area of research that has recently received increasing attention. In this study, the spontaneous shape change of 3D printed purple sweet potato purees of different formulations as triggered by microwave dehydration was investigated. The rheological properties, water distribution behavior, and dielectric properties of the purees were first studied. Addition of salt reduced the viscosity, storage modulus, loss modulus, and yield stress but increased the relaxation time of the purees. Addition of fructose syrup resulted in opposite results. Addition of both salt and syrup decreased the dielectric constant but increased the dielectric loss of the purees. Increased microwave power and salt content increased the rates of dehydration and deformation but decreased the maximum deformation degree of the printed samples. The syrup also decreased the maximum deformation degree. A desirable deformation pattern could also be achieved by manipulating the infill parameters. Transformation of two-dimensional planar flowers and butterflies into 3D configurations as a result of varying the aforementioned parameters is illustrated. The proposed technique to induce spontaneous shape change of a 3D printed starch-based product should lay a foundation for further application of four-dimensional food printing.